{"id":91,"date":"2018-02-08T17:40:54","date_gmt":"2018-02-08T17:40:54","guid":{"rendered":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/?page_id=91"},"modified":"2023-01-23T09:48:42","modified_gmt":"2023-01-23T09:48:42","slug":"des-in-polymerisation-reactions","status":"publish","type":"page","link":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/topics-of-research\/deep-eutectic-solvents-des\/des-in-polymerisation-reactions\/","title":{"rendered":"DES in polymerisation reactions"},"content":{"rendered":"
\n

The use of deep eutectic solvents (DESs) acting as all-in-one solvent\u2013template\u2013reactant systems offers an interesting green alternative to conventional syntheses in materials science. The use of DESs that contain not only the precursor itself but also some additional components that either provide certain functionality (e.g., drug delivery and controlled release, or electrical conductivity) to the resulting materials or direct their formation with a particular structure (e.g., hierarchical- type) offer an interesting economy of reagents. Moreover, DESs act as a reaction medium, so polymerizations are ultimately carried out in a solventless fashion.<\/p>\n

DESs also offer the possibility of using novel precursors \u2013 never used in conventional polymerizations \u2013 that either favor more efficient polymerization by decreasing the energy input required for reaction progress or allow introducing new funtionalities to the resulting materials.<\/p>\n

Representative examples included explored within the last years in our group include:<\/p>\n

    \n
  1. DES-assisted radical polymerizations of acrylates and methacrylates<\/li>\n
  2. DES-assisted formation of polyesters via polycondensation<\/li>\n
  3. DES-assisted formation of resorcinol-formaldehyde (using either resorcinol itself or in combination with other phenol derivatives) resins via polycondensation and preparation of 3D hierarchical porous materials<\/li>\n<\/ol>\n<\/div>\n

    The\u00a0 resulting DES-based materials have been optimised for their use in a wide variety of applications ranging from energy storage and conversion devices (supercapacitors and metal free electrodes for fuel cells) and environmental science technologies (gas adsorption and separation) to biomedicine.<\/p>\n

    Please refer to our selected list of publications to have a closer look to our research trajectory.<\/p>\n

    SELECTED LIST OF PUBLICATIONS<\/strong><\/div>\n
    <\/div>\n
    \n
      \n
    1. From polymer blends to a block copolymer: Ring-opening polymerization of L-lactide\/\u03b5-caprolactone eutectic system<\/span><\/a><\/strong>\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0<\/span>M. Castillo-Santillan, J. R. Torres-Lubian, A. Mart\u00ednez-Richa, S. T. Huerta-Marcial, M. C. Guti\u00e9rrez, K. Loos, M. G. P\u00e9rez-Garc\u00eda, J. D. Mota-Morales\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 Polymer 2022<\/strong>, 262, 125432.<\/span><\/li>\n
    2. Carbon-GO composites with preferential water versus ethanol uptake<\/span><\/a><\/strong> \u00a0\u00a0\u00a0\u00a0\u00a0 \u00a0 \u00a0 L. Z. Guan, J. Pati\u00f1o, C. Cuadrado-Collados, A. Tamayo, M. C. Guti\u00e9rrez, M. L. Ferrer, J. Silvestre-Albero, and F. del Monte\u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0ACS Applied Materials & Interfaces <\/cite>2019,<\/strong>11<\/em> (27), 24493-24503<\/span><\/li>\n
    3. Predicting the suitability of aqueous solutions of deep eutectic solvents for preparation of co-continuous porous carbons via spinodal decomposition processes<\/a>\u00a0<\/strong>
      \nE . Posada, N. L\u00f3pez-Salas, D. Carriazo, M. A. Mu\u00f1oz-M\u00e1rquez, C. O. Ania, R. J. Jim\u00e9nez-Riob\u00f3o, M. C. Guti\u00e9rrez, M. L. Ferrer, F. del Monte
      \nCarbon\u00a0<\/em>2017<\/strong><\/span><\/span>, 123,\u00a0<\/span>536-547<\/span><\/li>\n
    4. Phosphorus-doped carbon-carbon nanotube hierarchical monoliths as true three-dimensional electrodes in supercapacitor cells<\/a><\/strong><\/span>
      \nJ. Pati\u00f1o, N. Lopez-Salas, D. Carriazo, M. C. Gutierrez, M. L. Ferrer, F. del Monte
      \nJ. Mater. Chem. A<\/em> 2016<\/strong>, 4, 1251-1263<\/li>\n
    5. Efficient nitrogen-doping and structural control of hierarchical carbons using unconventional precursors in the form of deep eutectic solvents<\/a><\/strong><\/span>
      \nN. Lopez-Salas, M. C. Gutierrez, C. Ania, J. L. G. Fierro, M. L. Ferrer, F. del Monte
      \nJ. Mater. Chem. A<\/em> 2014<\/strong>, 2, 17387-17399<\/li>\n
    6. Deep Eutectic Solvents in Polymerizations: A Greener Alternative to Conventional Syntheses<\/a><\/span><\/strong>
      \nF del\u2005Monte, D.\u00a0Carriazo, M. C. Serrano, M.\u00a0C. Guti\u00e9rrez,\u00a0M. Luisa Ferrer ChemSusChem<\/em> 2014<\/strong>, 7, 999 \u2013 1009<\/li>\n
    7. Phosphate-Functionalized Carbon Monoliths from Deep Eutectic Solvents and their Use as Monolithic Electrodes in Supercapacitors<\/a><\/strong><\/span>
      \nD. Carriazo, M.\u00a0C. Guti\u00e9rrez, F.\u00a0Pic\u00f3, J.M. Rojo, J.L.G. Fierro, M.L. Ferrer, F.\u2005Monte ChemSusChem<\/em> 2012<\/strong>, 5, 1405 \u2013 1409<\/li>\n
    8. Synthesis of novel lidocaine-releasing poly(diol-co-citrate) elastomers by using deep eutectic solvents<\/a><\/strong><\/span>
      \nM. C. Serrano, \u00a0\u00a0M. C. Gutierrez, R. Jim\u00e9nez, M. L. Ferrer, F. del Monte
      \nChem. Commun.\u00a0<\/em>2012<\/strong>, 48, 579\u2013581<\/li>\n
    9. Deep Eutectic Solvents Playing Multiple Roles in the Synthesis of Polymers and Related Materials<\/a>\u00a0<\/strong>
      \nD. Carriazo, M. C. Serrano, M. C. Gutierrez, M. L. Ferrer,<\/span>\u00a0F. del Monte
      \n<\/span>Chem. Soc. Rev.<\/em>\u00a02012<\/strong>,\u00a041<\/em>, 4996 \u2013 5014<\/span><\/li>\n
    10. Deep Eutectic Assisted Synthesis of Carbon Adsorbents Highly Suitable for\u00a0 Low-Pressure Separation of CO2\/CH4 Gas Mixtures<\/a>\u00a0<\/strong>
      \nJ. Pati\u00f1o, M. C. Gutierrez, D. Carriazo, C. Ania, J. Parra,\u00a0M. L. Ferrer,\u00a0F. del Monte
      \nEnergy Environ. Sci.\u00a0<\/em>2012<\/strong><\/span><\/span>,\u00a05<\/span><\/em>,\u00a0<\/span>8699-8707<\/span><\/li>\n
    11. Deep Eutectic Solvents as Both Precursors and Structure Directing Agents in the Synthesis of Nitrogen Doped Hierarchical Carbons Highly Suitable for CO2 Capture<\/a><\/strong><\/span>
      \nM. C. Gutierrez, D. Carriazo, C. Ania, J. Parra, M. L. Ferrer, F. del Monte
      \nEnergy Environ. Sci.<\/em> 2011<\/strong>, 4, 3535-3544<\/li>\n
    12. Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium<\/a><\/strong><\/span>
      \nJ. D. Mora-Morales, M. C. Gutierrez, I. C. Sanchez, G. Luna-Barcenas, F. del Monte
      \nChem. Commun.\u00a0<\/em>2011<\/strong>, 47, 5328\u20135330<\/li>\n
    13. Resorcinol-Based Deep Eutectic Solvents as Both Carbonaceous\u00a0Precursors and Templating Agents in the Synthesis of Hierarchical Porous\u00a0Carbon Monoliths<\/span><\/strong><\/a>\u00a0
      \nD. Carriazo, M. C. Gutierrez, M. L. Ferrer,<\/span>\u00a0F. del Monte
      \nChem. Mater.<\/em>\u00a0<\/span>2010<\/strong><\/span>,<\/span>\u00a022<\/span><\/em>, 6146<\/span><\/span><\/li>\n<\/ol>\n<\/div>\n

       <\/p>\n

       <\/p>\n

       <\/p>\n

       <\/p>\n","protected":false},"excerpt":{"rendered":"

      The use of deep eutectic solvents (DESs) acting as all-in-one solvent\u2013template\u2013reactant systems offers an interesting green alternative to conventional syntheses in materials science. The use of DESs that contain not only the precursor itself but also some additional components that … Sigue leyendo →<\/span><\/a><\/p>\n","protected":false},"author":5,"featured_media":0,"parent":86,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"sidebar-page.php","meta":{"footnotes":""},"class_list":["post-91","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/pages\/91","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/comments?post=91"}],"version-history":[{"count":18,"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/pages\/91\/revisions"}],"predecessor-version":[{"id":648,"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/pages\/91\/revisions\/648"}],"up":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/pages\/86"}],"wp:attachment":[{"href":"https:\/\/wp.icmm.csic.es\/bioinspired-materials\/wp-json\/wp\/v2\/media?parent=91"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}