{"id":1282,"date":"2011-01-03T17:35:27","date_gmt":"2011-01-03T15:35:27","guid":{"rendered":"http:\/\/www.icmm.csic.es\/grupos\/?p=1282"},"modified":"2011-01-03T17:35:27","modified_gmt":"2011-01-03T15:35:27","slug":"an-atomistic-view-of-the-the-enantiomeric-recognition-of-pahs-on-single-crystal-metal-surfaces","status":"publish","type":"post","link":"https:\/\/wp.icmm.csic.es\/esisna\/2011\/01\/03\/an-atomistic-view-of-the-the-enantiomeric-recognition-of-pahs-on-single-crystal-metal-surfaces\/","title":{"rendered":"An atomistic view of the the enantiomeric recognition of PAHs on single crystal metal surfaces"},"content":{"rendered":"<p>Recently published in <a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/chem.201002079\/abstract\">Chemistry, a European Journal<\/a>. Vacuum deposition of a planarized PAH, as C60H30 , on a single-crystal surface, as Pt(111), leads to surface induced chirality caused by the different landing side of the molecule, as depicted by in-situ STM images.<\/p>\n<p style=\"text-align: center\"><a href=\"https:\/\/wp.icmm.csic.es\/esisna\/wp-content\/uploads\/sites\/26\/2011\/01\/toc_cmyk.gif\"><img loading=\"lazy\" decoding=\"async\" class=\"size-medium wp-image-1283 aligncenter\" src=\"https:\/\/wp.icmm.csic.es\/esisna\/wp-content\/uploads\/sites\/26\/2011\/01\/toc_cmyk.gif\" alt=\"\" width=\"210\" height=\"198\" \/><\/a><\/p>\n<p><span lang=\"EN-GB\">We show that the surface discriminate the landing side of an individual molecule. Molecules adsorbed \u201cright\u201d or \u201cleft\u201d-hand present different structural geometries, shifted by about 35\u00ba between them.<span> <\/span>Large-scale DFT calculations explain the <strong><a href=\"http:\/\/www.icmm.csic.es\/grupos\/?page_id=1290\">atomistic mechanism behind the enantiomeric recognition process<\/a><\/strong>.<\/span><!--EndFragment--><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Recently published in Chemistry, a European Journal. Vacuum deposition of a planarized PAH, as C60H30 , on a single-crystal surface, as Pt(111), leads to surface induced chirality caused by the different landing side of the molecule, as depicted by in-situ STM images. We show that the surface discriminate the landing\u2026<\/p>\n<p> <a class=\"continue-reading-link\" href=\"https:\/\/wp.icmm.csic.es\/esisna\/2011\/01\/03\/an-atomistic-view-of-the-the-enantiomeric-recognition-of-pahs-on-single-crystal-metal-surfaces\/\"><span>Continue reading<\/span><i class=\"crycon-right-dir\"><\/i><\/a> <\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[1],"tags":[10,19,33],"class_list":["post-1282","post","type-post","status-publish","format-standard","hentry","category-sin-categoria","tag-dft","tag-nano","tag-stm"],"_links":{"self":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/1282","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/comments?post=1282"}],"version-history":[{"count":0,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/1282\/revisions"}],"wp:attachment":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/media?parent=1282"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/categories?post=1282"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/tags?post=1282"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}