{"id":3960,"date":"2021-06-24T14:02:19","date_gmt":"2021-06-24T14:02:19","guid":{"rendered":"https:\/\/wp.icmm.csic.es\/esisna\/?p=3960"},"modified":"2021-06-24T14:02:19","modified_gmt":"2021-06-24T14:02:19","slug":"lanthanide-porphyrin-species-as-kondo-irreversible-switches-through-tip-induced-coordination-chemistry-nanoscale-2021","status":"publish","type":"post","link":"https:\/\/wp.icmm.csic.es\/esisna\/2021\/06\/24\/lanthanide-porphyrin-species-as-kondo-irreversible-switches-through-tip-induced-coordination-chemistry-nanoscale-2021\/","title":{"rendered":"Lanthanide-porphyrin species as Kondo irreversible switches through tip-induced coordination chemistry (NANOSCALE 2021)"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"size-medium wp-image-3961 aligncenter\" src=\"https:\/\/wp.icmm.csic.es\/esisna\/wp-content\/uploads\/sites\/26\/2021\/06\/Kondo_redes-300x119.png\" alt=\"\" width=\"300\" height=\"119\" srcset=\"https:\/\/wp.icmm.csic.es\/esisna\/wp-content\/uploads\/sites\/26\/2021\/06\/Kondo_redes-300x119.png 300w, https:\/\/wp.icmm.csic.es\/esisna\/wp-content\/uploads\/sites\/26\/2021\/06\/Kondo_redes-150x60.png 150w, https:\/\/wp.icmm.csic.es\/esisna\/wp-content\/uploads\/sites\/26\/2021\/06\/Kondo_redes.png 393w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/p>\n<p>Metallosupramolecular chemical protocols are applied to\u00a0<em>in situ<\/em>\u00a0design dysprosium porphyrin complexes on Au(111) by sequential deposition of 2H-4FTPP species and Dy, resulting in the production of premetallated Dy-2H-4FTPP, partially metallated Dy-1H-4FTPP and fully metallated Dy-0H-4FTPP complexes, as determined by scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. A zero bias resonance is found in the Dy-2H-4FTPP species which, upon study of its spatial distribution and behavior with temperature, is assigned to a Kondo resonance resulting from an unpaired spin in the\u00a0<em>molecular<\/em>\u00a0backbone, featuring a Kondo temperature (<em>T<\/em><small><sub>K<\/sub><\/small>) of \u2248 21 K. Notably, the Kondo resonance can be switched off by removing one hydrogen atom of the macrocycle through tip-induced voltage pulses with submolecular precision. The species with this Kondo resonance can be laterally manipulated illustrating the potential to assemble artificial Kondo lattices. Our study demonstrates that the pre-metallation of macrocycles by lanthanides and their controlled manipulation is a novel strategy to engineer\u00a0<em>in situ<\/em>\u00a0tunable Kondo nanoarchitectures, enhancing the potential of coordination chemistry for spintronics.<\/p>\n<p>Full text in this link (<span style=\"color: #0000ff\">https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2021\/nr\/d0nr08992c#!divAbstract<\/span>)<\/p>\n<div class=\"article__title\">\n<p class=\"capsule__title fixpadv--m\"><strong>Lanthanide-porphyrin species as Kondo irreversible switches through tip-induced coordination chemistry<\/strong>, <span class=\"article__author-link\">B. Cirera, <\/span><span class=\"article__author-link\">J. M. Gallego, <\/span><span class=\"article__author-link\">J. I. Mart\u00ednez,\u00a0<\/span><span class=\"article__author-link\">R. Miranda, <\/span><span class=\"article__author-link\">D. \u00c9cija, Nanoscale 13, 8600-8606 (2021).<\/span><\/p>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>Metallosupramolecular chemical protocols are applied to\u00a0in situ\u00a0design dysprosium porphyrin complexes on Au(111) by sequential deposition of 2H-4FTPP species and Dy, resulting in the production of premetallated Dy-2H-4FTPP, partially metallated Dy-1H-4FTPP and fully metallated Dy-0H-4FTPP complexes, as determined by scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. A zero\u2026<\/p>\n<p> <a class=\"continue-reading-link\" href=\"https:\/\/wp.icmm.csic.es\/esisna\/2021\/06\/24\/lanthanide-porphyrin-species-as-kondo-irreversible-switches-through-tip-induced-coordination-chemistry-nanoscale-2021\/\"><span>Continue reading<\/span><i class=\"crycon-right-dir\"><\/i><\/a> <\/p>\n","protected":false},"author":96,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[50,49,48,51],"tags":[10,18,33,34],"class_list":["post-3960","post","type-post","status-publish","format-standard","hentry","category-dft","category-molecules","category-stm","category-surfaces","tag-dft","tag-molecules","tag-stm","tag-surfaces"],"_links":{"self":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/3960","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/users\/96"}],"replies":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/comments?post=3960"}],"version-history":[{"count":2,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/3960\/revisions"}],"predecessor-version":[{"id":3963,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/3960\/revisions\/3963"}],"wp:attachment":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/media?parent=3960"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/categories?post=3960"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/tags?post=3960"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}