{"id":3969,"date":"2021-06-24T14:19:08","date_gmt":"2021-06-24T14:19:08","guid":{"rendered":"https:\/\/wp.icmm.csic.es\/esisna\/?p=3969"},"modified":"2021-06-24T14:35:49","modified_gmt":"2021-06-24T14:35:49","slug":"dysprosium-directed-metallosupramolecular-network-on-graphene-ir111-chem-commun-2021","status":"publish","type":"post","link":"https:\/\/wp.icmm.csic.es\/esisna\/2021\/06\/24\/dysprosium-directed-metallosupramolecular-network-on-graphene-ir111-chem-commun-2021\/","title":{"rendered":"Dysprosium-directed metallosupramolecular network on graphene\/Ir(111) (CHEM. COMMUN. 2021)"},"content":{"rendered":"

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The interest in exploiting the unique properties of lanthanides has led to the recent design of two-dimensional coordination networks incorporating f-block elements on metallic surfaces. In order to take this field to the next step of progression, it is necessary to electronically decouple these two-dimensional architectures from the metallic surface underneath. As a first step in this direction, we report the formation of dysprosium-directed metal\u2013organic networks employing three-fold ligands as molecular linkers equipped with terminal carbonitrile functional groups on weakly interacting substrates such as Au(111) and graphene\/Ir(111). We observe on both substrates identical quasi-hexagonal Dy\u2013carbonitrile coordination networks based on majority five-fold nodes. Our findings provide perspectives for the formation of lanthanide coordination networks on graphene and related sp2<\/sup><\/small>\u00a0materials grown on metals.<\/p>\n

Full text in this link (https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2021\/cc\/d0cc07315f#!divAbstract<\/a><\/span>)<\/p>\n

Dysprosium-directed metallosupramolecular network on graphene\/Ir(111)<\/strong>, Daniel Moreno, <\/span>Borja Cirera,\u00a0<\/span>Sofia O. Parreiras, <\/span>Jos\u00e9 I. Urgel,\u00a0<\/span>Nelson Gim\u00e9nez-Agull\u00f3,\u00a0<\/span>Koen Lauwaet,\u00a0<\/span>Jos\u00e9 M. Gallego, <\/span>Jos\u00e9 R. Gal\u00e1n-Mascar\u00f3s,\u00a0<\/span>Jos\u00e9 I. Mart\u00ednez,<\/span> Pablo Ballester,<\/span> Rodolfo Miranda, <\/span>David \u00c9cija<\/span>, Chem. Commun.<\/i>, 57, 1380-1383 (2021).<\/span><\/div>\n","protected":false},"excerpt":{"rendered":"

The interest in exploiting the unique properties of lanthanides has led to the recent design of two-dimensional coordination networks incorporating f-block elements on metallic surfaces. In order to take this field to the next step of progression, it is necessary to electronically decouple these two-dimensional architectures from the metallic surface\u2026<\/p>\n

Continue reading<\/span><\/i><\/a> <\/p>\n","protected":false},"author":96,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[50,49,48,51],"tags":[10,18,33,34],"class_list":["post-3969","post","type-post","status-publish","format-standard","hentry","category-dft","category-molecules","category-stm","category-surfaces","tag-dft","tag-molecules","tag-stm","tag-surfaces"],"_links":{"self":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/3969","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/users\/96"}],"replies":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/comments?post=3969"}],"version-history":[{"count":3,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/3969\/revisions"}],"predecessor-version":[{"id":3973,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/3969\/revisions\/3973"}],"wp:attachment":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/media?parent=3969"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/categories?post=3969"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/tags?post=3969"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}