{"id":4297,"date":"2023-03-28T14:29:56","date_gmt":"2023-03-28T14:29:56","guid":{"rendered":"https:\/\/wp.icmm.csic.es\/esisna\/?p=4297"},"modified":"2024-04-18T13:51:15","modified_gmt":"2024-04-18T13:51:15","slug":"the-influence-of-reaction-conditions-on-the-growth-of-mofs-on-surfaces","status":"publish","type":"post","link":"https:\/\/wp.icmm.csic.es\/esisna\/2023\/03\/28\/the-influence-of-reaction-conditions-on-the-growth-of-mofs-on-surfaces\/","title":{"rendered":"The influence of reaction conditions on the growth of MOFs on surfaces"},"content":{"rendered":"

The importance of the reaction conditions has been confirmed in this study, where following an on-surface synthesis approach on the same surface and with the same precursor, two different metal-organic frameworks were obtained. The distinction comes from the different synthesis protocol of the controlled growth of both metal-organic nanostructures. Thus, the organic precursors, p-AP molecules, form either a honeycomb or a Kagome metal organic framework on Cu(111), where the presence of adatoms is essential. This research evidences the competition between kinetic and thermodynamic mechanisms in the formation process of metal-organic frameworks on surfaces.<\/p>\n

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You can find the work published in open access in:<\/p>\n
N. Ruiz del \u00c1rbol, C. S\u00e1nchez-S\u00e1nchez, J. I. Mart\u00ednez, L. Rodr\u00edguez, D. Serrate, A. Verdini, L. Floreano, P. Jacobson, L. Grill, J. A. Mart\u00edn-Gago, M. F. L\u00f3pez, \u201cOn-surface synthesis of metal-organic frameworks: the critical role of the reaction conditions\u201d Chem. Commun., 59 (2023) 2954. DOI: 10.1039\/D3CC00185G<\/a><\/p>\n<\/div>\n","protected":false},"excerpt":{"rendered":"
The importance of the reaction conditions has been confirmed in this study, where following an on-surface synthesis approach on the same surface and with the same precursor, two different metal-organic frameworks were obtained. The distinction comes from the different synthesis protocol of the controlled growth of both metal-organic nanostructures. Thus,\u2026<\/p>\n
 Continue reading<\/span><\/i><\/a> <\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[50,49,48,51],"tags":[18,19,34],"class_list":["post-4297","post","type-post","status-publish","format-standard","hentry","category-dft","category-molecules","category-stm","category-surfaces","tag-molecules","tag-nano","tag-surfaces"],"_links":{"self":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/4297","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/comments?post=4297"}],"version-history":[{"count":5,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/4297\/revisions"}],"predecessor-version":[{"id":4572,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/posts\/4297\/revisions\/4572"}],"wp:attachment":[{"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/media?parent=4297"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/categories?post=4297"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wp.icmm.csic.es\/esisna\/wp-json\/wp\/v2\/tags?post=4297"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}