Surface symmetry and reactivity rule the room-temperature adsorption of p-aminophenol (J. Phys. Chem. C 2020)
Molecular chemisorption on metal surfaces has attracted great interest over the past decades. Both the characteristics of the adsorbed molecules and the surface properties govern the chemisorption processes. We have studied the role of the nature and symmetry of different metallic surfaces, Cu(110), Cu(111) and Pt(111), on the room-temperature adsorption…
Decoupling of PVD graphene by controlled oxygen intercalation (App. Surf. Sci. 2020)
In the last decade after graphene isolation in 2004, many methods have been developed for the synthesis of this material. The most used substrates have been metal surfaces, due to their catalytic action, which is helpful for the formation of graphene. However, the coupling of the graphene layer with the…
The interaction of atomic carbon and acetylene investigated with STARDUST (Astrophys. J. 2020)
Background image: Spiral structure around the red giant star R Sculptoris. Credit: ALMA (ESO/NAOJ/NRAO)/M. Maercker et al. The formation of interstellar carbon dust in dying stars is still not fully understood. In particular, the interaction of atomic carbon with the most abundant chemical species in the atmosphere of red…
Unconventional science by unconventional people
Time flies. Nearly 20 years have passed since Javier Mendez, Pedro de Andrés, Paqui López and myself decided to apply jointly to the national plan projects and to share all resources and instrumentation, setting the bases of our research group. In this period, our lab consisted of an inherited UHV…
First results of astrophysical relevance obtained with the Stardust (Nat. Astron. 2020)
The first results of astrophysical relevance obtained with the Stardust machine evidence a prevalence of non-aromatic species in the inner regions of circumstellar envelopes Image taken from https://www.bbvaopenmind.com/ciencia/fisica/un-viaje-a-la-ultima-frontera-i-las-atmosferas-de-las-estrellas/ This work is part of the results obtained in the framework of the European project ERC…
From the kitchen to the lab (2D Materials 2019)
We have developed a simple method to reversibly decouple the graphene form a metal substrate by Na intercalation. This strategy is based on the photo-dissociation of a previously adsorbed NaCl layer on graphene. Upon a short exposure to an X-Ray beam, the NaCl molecules break, the chlorine desorbs and the…
Inducing Intermolecular C-C Covalent Bonds between PAHs by Exposure to Atomic Hydrogen (JACS 2019)
The ESISNA group, in collaboration with the Nanotech@surfaces group from Empa (Switzerland), has demonstrated the catalytic role that atomic hydrogen can play in the formation of new intermolecular C-C covalent bonds on relatively inert surfaces. For this purpose, we have annealed a Au(111) surface, previously covered with different PAHs, in…
Comparative structural characterization of two types of graphene layers on SiC (Appl. Surf. Sci. 2019)
We have studied epitaxial graphene grown on SiC by chemical vapour deposition. In the work, two kinds of graphene layers were evaluated, a single layer graphene and a quasi-free-standing graphene obtained by hydrogen intercalation under the buffer layer. To evaluate the influence of the different nature of both graphene layers…
ESISNA at the «On-Surface Synthesis» international workshop 2018
On-surface synthesis is nowadays a promising and potential strategy for the development of novel nanomaterials. This approach allows not only to achieve materials of different dimensionalities such as 0D nanoobjects, 1D nanowires or even 2D networks for diverse applications but also the possibility to manipulate the molecules at the atomic…
On-surface chemistry: synthesis of azine derivatives with acceptor behaviour (Angew. Chem. 2018)
On-surface chemistry is a potential strategy focused on obtaining and developing novel nanomaterials of different dimensionalities with atomic precision. The growth mechanism is based on a bottom-up approach where molecular building blocks are evaporated onto a surface. Therefore, choosing the appropriate surface and precursor we are able to build and…